Doan equalised in the 75th minute before Asano showed lovely control and smashed the winner in from a tight angle -- causing an explosion of joy among the Japan bench and head shaking among German fans used to watching both players ply their trade in the Bundesliga.
Bayern Munich defender Philipp Lahm will captain Germany in place of injured Michael Ballack and Manuel Neuer will be the starting goalkeeper at next month's World Cup, coach Joachim Loew said.
Schalke 04 won 2-1 at struggling VfB Stuttgart to stay on the heels of the Bundesliga leaders on Saturday while Bayern Munich notched their first victory in three games with a 2-1 triumph at Freiburg.
A summary of Tuesday's Champions League first leg quarter-finals between Arsenal and Real Madrid, and Inter Milan and Bayern Munich.
The Germans were desperate to impress in front of a home crowd to make amends for their shock 2018 World Cup first-round exit, but instead they rarely broke through the French rearguard.
Chelsea consolidated top spot in Champions League Group B with a 2-0 win over Schalke 04 at Stamford Bridge on Wednesday.
A summary of sports events and sports persons, who made news on Wednesday.
Late Tchouameni header gives Real Madrid 2-1 Las Palmas win and top spot
Images from the Euro 2024 Group A match between Switzerland and Germany, in Frankfurt, on Sunday.
Bayern Munich wasted a two-goal lead and needed a lucky 82nd- minute winner from Joshua Kimmich to beat Borussia Dortmund 3-2 in Germany's Super Cup on Wednesday and secure their fifth title of the year.
A round-up of Wednesday's UEFA Champions League last-16 first leg matches.
Two goals from Marco Reus spurred Borussia Dortmund to lift the German Super Cup with a 4-2 win over Champions League and Bundesliga holders Bayern Munich on Saturday.
Bundesliga leaders Bayern Munich crushed Freiburg 4-0 on Saturday, recording their 13th successive Bundesliga victory and extending their league unbeaten streak to 46.
Germany coach Joachim Loew has named four talented youngsters, including three uncapped players, in his preliminary 27-man squad for Euro 2016.
Real Madrid's Welsh winger Gareth Bale has joined Lionel Messi and Cristiano Ronaldo in the race for FIFA's Ballon d'Or award.
IMAGES from the UEFA Champions League matches played on Wednesday
A summary of Tuesday's first leg quarter-final action in the UEFA Champions League.
A breathtaking individual goal from Saul Niguez put Atletico Madrid in the box seat in their Champions League semi-final against Bayern Munich with a 1-0 victory in a tense first leg on Wednesday.
Ciro Immobile scored a 69th-minute penalty to earn hosts Lazio a 1-0 victory over 10-man Bayern Munich.
Germany came to Qatar with a leaky defence that had not kept a clean sheet in a competitive game
Bayern Munich gained some revenge for their 2012 Champions League final defeat by Chelsea when they beat the Premier League club 5-4 on penalties after a thrilling UEFA Super Cup ended 2-2 at the end of extra-time on Friday.
Ronaldo helped Real Madrid to a second consecutive Champions League title and finished as the tournament's top scorer with 12 goals earlier this year.
Bayern Munich forward Thomas Muller has stated that 'it would be almost boring' to see Portuguese international Cristiano Ronaldo winning the prestigious Ballon d'Or award yet again.
Beat Mexico's Tigres 1-0 to win their sixth title.
IMAGES from the Champions League quarter-final played between Barcelona and Bayern Munich in Lisbon on Friday.
Winger Marco Reus was left out of World Cup winners Germany's final Euro 2016 squad on Tuesday over injury concerns, coach Joachim Loew said.
Atletico Madrid reached the Champions League final on away goals on Tuesday after a 2-1 defeat at Bayern Munich, in which both sides missed a penalty, with the exhilarating tie finishing 2-2 on aggregate.
With the group standings flashing on the big screen of the Al Bayt stadium, Germany grew nervous with Musiala twice hitting the post early in the second half.
Strikes from Freiburg's Ritsu Doan and VfL Bochum's Takuma Asano, who struck from fellow Bundesliga player Ko Itakura's deep free kick, gave the Asians their first ever win over Germany.
Real's Cristiano Ronaldo will be going in search of his third consecutive World Player of the Year award
Croatian forward Ante Budimir scored twice to help Osasuna earn a shock 4-2 home win over leaders Barcelona.
Two goals from Antoine Griezmann helped hosts France overcome world champions Germany 2-0 on Thursday to reach the final of Euro 2016, a first competitive victory over their old rivals in 58 years. Twice winners France will face Portugal in Sunday's final in Paris after defending stoutly against a Germany side who dominated possession but conceded a needless first-half penalty before being picked off on the break in the second period.
Barcelona won 3-1 at Alaves in La Liga on Saturday thanks to goals by Robert Lewandowski, Ilkay Gundogan and substitute Victor Roque, who was sent off after picking up a second yellow card.
Bayern Munich came from a goal down at home to beat Ingolstadt 3-1 on Saturday and make it three wins in three Bundesliga matches as they went two points clear at the top. The champions were far less convincing than in their Champions League 5-0 win over Rostov on Tuesday and were caught napping after eight minutes with Paraguayan Dario Lezcano slipping the ball through the legs of Manuel Neuer.
Midfielder Bastian Schweinsteiger won his 121st cap in his last match for Germany as they beat Finland 2-0 in an international friendly in Moenchengladbach on Wednesday.
Images from Saturday's action in the Nations League group stage matches.
IMAGRS from the soccer matches played across European leagues on Friday
Bayern Munich won its sixth Champions League crown in Lisbon on Sunday night.
Barcelona forward Lionel Messi raised eyebrows when he said in passing on Monday that he did not know where he would be next year.
The 25-year-old striker, who stands 1.76 metres tall, caught the eye on the big stage against Germany, driving home a penalty at the end of the first half before poking in the ball on 72 minutes following a rare blunder by Germany goalkeeper Manuel Neuer.